Self-explanatory.
Yes. Multiple times actually.
Landorus: http://bulbapedia.bulbagarden.net/wiki/Landorus-EX_%28Boundaries_Crossed_89%29
Thundurus: http://bulbapedia.bulbagarden.net/wiki/Thundurus-EX_%28Thunder_Knuckle_20%29
Tornadus: http://bulbapedia.bulbagarden.net/wiki/Tornadus-EX_%28Thunder_Knuckle_46%29
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