PokéBase - Pokémon Q&A
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Self explanatory

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2 Answers

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theres quite alot but the only few I can remember are chatot,buizel,lucario,zorua,zoroark and ho-oh

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On my account, you could play enough of the current version to see a Pokemon before it appears in the show, this accounts for all current Pokemon. The only Pokemon that I could remember seeing before I saw it in the game(s) was Spearow of the very first episode of Pokemon, excluding Pikachu.

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chatot,buizel,lucario, and zoura