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In which episode does charmander evolve?

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Ash's Charmander?

It evolved into Charmeleon in March of the Exegguror Squad.
It then evolved into Charizard in Attack of the Prehistoric Pokemon.

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Ash's Charmander evolved into Charmeleon in March of the Exeggutor Squad. It quickly grew unruly and disobedient and evolved into Charizard soon after, in Attack of the Prehistoric Pokémon.

Source: Bulbapedia

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