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(I'm just pointing out) You can find a Dusklops at lv.39 right after you beat Giratina in Distortion world.

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It's because night starts at 8:00, and Duskull can only be found at night there.

There is a 20% chance of finding a level 17-20 Duskull on all floors (1-5F).

Hope I helped! :)

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but that was for gen. II... Oops