PokéBase - Pokémon Q&A
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I have tried with both male and female combinations but it is still not working.

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1 Answer

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Piplup, nor Prinplup can learn Stealth Rock via breeding.

In Generation IV, it can learn Stealth Rock via TM76.
In Generation V, it can learn it via the Move Tutor.

Hope I helped. :)
Source: Serebii

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What about empoleon?
you can't breed an empoleon.  piplup will come out of the egg no mather what
To add to Indigo's answer, if you breed a Female Swinub with a Male Prinplup the Swinub that hatches from the egg will have Stealth Rock as long as the Male Prinplup has it. But if you breed a Female Prinplup with a Male Swinub even if the Swinub has Stealth Rock the Piplup that hatches from the egg will not have Stealth Rock.
'Cos Stealth Rock ain't one of it's Eggy moves. :3