PokéBase - Pokémon Q&A
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Say I use their w/ a Pokemon that has no item on a Pokemon w/ a Focus sash, Do I take the sash and KO Them?
Do I activate the sash then take it? (Such glitch ;0;)
Or Do I simply activate and break the sash?

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If the target's consumable held item is triggered by Thief, such as a Colbur Berry or Focus Sash, it will not be stolen.

http://bulbapedia.bulbagarden.net/wiki/Thief_(move)

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