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I got two Pikachus from Wonder Trade a couple days ago. Both know Volt Tackle, and one is male and the other is female. If I breed them together, will the baby know Volt Tackle too, or does one of the Pikachus need the Light Ball to hold?

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As long as one of the parents hold a Light Ball, Pichu is guaranteed to have Volt Tackle.

Hope I helped. :)
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Thanks!  I didn't know that the Light Ball was mandatory even if both parents knew Volt Tackle.
Uh, if you gave a Ditto the Light Ball, I'm pretty sure it wouldn't work (Assuming one of the parents is a Ditto)
"The only way for Pichu to hatch knowing Volt Tackle is for one of the parents to hold a Light Ball." ~ Above Source. :3

But in this case, the parents are both Pikachus, so that wouldn't matter. xD