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I heard you can catch Phione in Diamond, but I am not sure. Is it true? If it is, where and how do I catch it? Please help me! Thank you! :)

Note: Horrible Speller, so sorry for any grammer or spelling mistakes!

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No, it is not possible to catch phione, as it is the offspring of Manaphy.
You must breed Manaphy with Ditto to get Phione.

Source: Experience and this.

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Ok, thanks! :)
Glad I could help!