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If I have a spare room in my party and Nincada evolves into Ninjask I would get a Shedinja. If I only had a Master ball in my bag would the Shedinja use the Master Ball?

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No it has to be an ordinary Poké Ball.

>Shedinja is considered a "special" evolution of Nincada, appearing only when Nincada evolves into Ninjask, starting at level 20, and there is an extra space in the player's party and the player has an extra Poké Ball.

>From Generation IV onwards, a basic Poké Ball (a requirement for evolution) is removed from the bag upon evolution to produce a Shedinja.

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Okay thanks
Your welcome.