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I have a Chandelure that can take out a mega Aggron with no Sp.Def, but can just barely not take it out if it had max (nature included) Sp.Def. Obviously a Mega Aggron wouldn't use a SpDef nature, but do Aggron users typically invest in SpDef?
If you could include an entire set that would be great too.

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The sp.def investment is usuallu staple, to make it a more well rounded wall/tank.

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Mega aggrons generally prefer Impish or Relaxed (trick room, also makes aggron us slower than Aegislash). Since such aggrons like to spread status like t-wave and toxic, a bulky spread is suggested:
248 HP/ 252 Sp.Def/8 Def

Offesive variants prefer Adamant or Brave natures. Recommended set would be something like:
252 HP/252 Atk/4 Def (with 0 IVs in speed if trick room, but good IVs if Rock polish).

Hope I helped!

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