PokéBase - Pokémon Q&A
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In each game please

P.S. Don't just go Saying Magikarp. Just No

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Ok....
Magikarp. XD

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There are several.

For eg.- Litwick in the first few floors of Celestial Tower in Black 2, and Unown in the Ruins.of Alph are both Pokemon, who are found at a 100% rate.

There are many such examples, see more examples [here.][1]

Hope I helped!
[1]: http://pokemondb.net/pokebase/203837/places-black-pokemons-100%-100%-wild-encounter-repel-tricks

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Good one. :D