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When do you recieve the Masterball from Professer Juniper?

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After you obtain your eighth badge, and is well on your way to the Pokemon League, she will stop by to hand it to you.

(I apologize, I forgot the name of the city with the neon lights and floors everywhere, I'm still getting used to the new names.)

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You get it after you beat the Oplucids Gym leader and when you get to the Gate leading to the Victory Road/Pokemon League, Professer Juniper will Come by and then Give it to you

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