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How do I add Rotom to my Pokedex in Platinum?

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I know he's in the TV in the Old Chateau and I have already defeated the Elite Four. Does he only appear at night? If I need the Sinnoh Dex completed first, then how (he's the only one I'm missing)?

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It only appears at nighttime. However, you are able to catch it before the Elite Four!

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