PokéBase - Pokémon Q&A
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If you had a full PC, full Pokebank, Party, etc. so you have the max number of Pokemon, what will happen if you try to split a B/W Kyurem into Reshiram/Zekrom and Kyurem? If no one has tried this, at least what happens if you try to catch another Pokemon?

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Nothing will happen if you try to separate White/Black Kyurem when you have a full PC because you can only separate White/Black Kyurem while it is in your party. If your party is full, nothing happens.
As for catching Pokemon when your PC boxes and party is full, you are unable to.

Hope this helps!

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Thanks! I'd I've never owned Black/sWhite 2 so  couldn't try it myself.