PokéBase - Pokémon Q&A
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Some can be unnamed. Because they might just have different colors like some Balls in Master Quest (or the Johto Series)

The one I know of is GS Ball (it was in the games too but nobody really knew about it so it counts as an anime exclusive imo)

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pretty sure that's it. just the gs ball

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The GS Ball is the only anime exclusive PokeBalls.

But if count movie as an anime,then the 2 anime exclusive PokeBalls are:

1)GS Ball
2)Dark Ball
3)Mewtwo Ball
4)Old Ball

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Dark ball

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Mewtwo Ball

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old ball

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GS Ball

Source1
Source2

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What about Mewtwo's balls he uses in Mewtwo Strikes Back?
thanks,i almost forgot about it,i dont know why it is not there in bulbapedia.
please let me know if i missed any exclusive pokeballs.
I have seen some PokeBalls with miscolors as well, as I mentioned in my question I count miscolors as anime exclusive Balls too