So what I mean is; when do daily events in the games (my case Pokemon Black and White) reset?
is it every day at 12am, is it a FULL day of 24 hours, or a different time?
if it applies only to specific games, please state that!
It resets every day at midnight.
Source: Experience and testing.
I believe it's 24 hours from the last time you accessed it. So, say you went on the Dream World to befriend a Pokemon at 6:00 pm on Saturday, you wouldn't be able to do that again until 6:00 pm on Sunday.
Dream world access you have to wait 24 hours for.
In game events, like the patrat cups game on marvelous bridge, i've always just gone sometime after midnight and never had a problem doing them no matter when i last did it.
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