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if a chansey and blissey both have evs 252 defense and special defense but chansey holds a eviolite will chansey's defense and special defense be more than blissey's?

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Blissey's S. Defense caps out at 405 with beneficial nature. Blissey's Defense caps out at 130 with beneficial nature. Chansey's S.Defense caps out at 339 with beneficial nature, with Eviolite it gets about 508 which is more than Blissey's by over a hundred (103 to be exact). Chansey's Defense with beneficial nature caps out at 119, with Eviolite that becomes about 178 which is a bit higher than Blissey's. Chansey gets higher defenses with the Eviolite. Hope I helped :)

Note: Eviolite gives a 1.5 boost to the defenses of not fully evolved Pokemon.
Note: you can not have a beneficial nature to two stats at once.

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thx it really helped me :D
No problem :D
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The chansey holding the eviolte defence and special defence would be doubled so it would have higher defence and special defence stats.

Hope this helps and good luck

Edit: I apolgise evoilite only offers a 1.5x boost

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Not doubled. 1.5x increase.