PokéBase - Pokémon Q&A
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Yes you can.
here is a video http://www.youtube.com/watch?v=y9dM0UDD7c4&feature=player_embedded of a shiny sudowoodo.
Also if that is not enough here is a bulbipedia source
http://bulbapedia.bulbagarden.net/wiki/Shadow_Pokémon

If you want a shiny Pokemon it is really hard in colesseum saying there are no wild pokes so shadows have a strange glitch explained on my source but in xd gale of darkness Pokemon at pokespots are wild so the normal chance aplies to them.

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Ok Absol i give in so i will hide my answer and upvote yours Well Done *Grrrrrrrrr*
Wait there is still hope josh agrees with me
bulbapedia trumps Josh from a year ago.
yay, thanks
Lawl, Trachy xD