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I heard somewhere that Mewtwo is the hardest Pokemon to catch. Is this true or was it just something from the anime?

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No, it has a catch rate of 3 which it shares with other Pokemon. So technically they are all the hardest to catch.

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I caught zygarde with a great ball.
I caught kyurem in a pokeball after 70ish thrown.
For me, Heatran was hard, and I caught Mewtwo in a regular Pokeball!
I did too and I didn't even battle it I just throw a poke ball at mewtwo on first turn and I catch it.
@dacidsauce lol that is a big lie