PokéBase - Pokémon Q&A
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After you beat the E4.
Black&White:N
Diamond,Pearl&Platinum:Barry
Heartgold&Soulsilver:Whatever you named him

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Best answer
  • Black and White: First time, yes, in his castle. Second time: No.
  • Diamond / Pearl / Platinum: yes, Fight Area on weekends, Stark Mountain.
  • HeartGold / SoulSilver: Pokemon League on Wednesdays, Dragon's Den
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Thanks
how about bw2 (hugh)