Wobbuffet is a weird Pokemon. Since we all know what the moveset would be, it can't really change what the best Evs and nature is.
Bold/Impish/Relaxed - 252HP/94Def/164SpDef
Calm/Careful/Sassy - 252HP/160Def/98SpDef
Makes 584 HP, 192 Def and 193 SpDef with perfect IVs
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