PokéBase - Pokémon Q&A
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Because I want to poison the opponent while saving a spot for something besides Toxic.

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You can use the move Fling [exactly what you wanted!] (throws your held item at target, inflicting damage and effects of the held item), or use the move Switcheroo (switches the item of your own and the opponents).

Source: I use this trick on my Ambipom, works well with Facade.

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Thanks!
Always happy to help!