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it is Executive Archer which you battle at the top of Radio Tower. He has a Houndour and a Koffing at level 35. He also has a Houndoom at level 38.

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weakest antagonist boss in the entire pokemon game
Hes not the Antagonist your rival is
well, antagonist has several meanings, it can be a rival, or it can be the "bad guys"
Your rivals aren't necessarily bad
hes still not the antagonist  you only see him once
I never said HE is the antagonist, I said that he is the BOSS of the antagonists, team rocket