PokéBase - Pokémon Q&A
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Other than Vaporeon, Jolteon, Flareon, Espeon, Umbreon, Leafeon and Glaceon.

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There was no Eeveelution introduced in Generation 5. However, in Generation 6, a new Eeveelution was indeed brought into the games. Sylveon, a Fairy-type Pokemon, evolves from Eevee while knowing a Fairy-type move, along with two or more levels of Affection.

As of Generation 9, Sylveon is the most recent Eeveelution to have been introduced.

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You mean in Black and White? I think it's not! not from all region have eeveelution... for example like Hoenn, it doesn't have it!

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No sadly there are no new new eevee evolutions in black and white:( all of the new pokemon have been revealed.

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