PokéBase - Pokémon Q&A
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It made me think, maybe its the sunlight that'd make Eevee evolve.

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In some ways that would make more sense. But yes, if you're in a cave Eevee will still evolve into Espeon during the day.

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During daytime, yes, EEVEE will evolve to ESPEON. But it's friendship must be high. Try giving it a Soothe Bell.

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