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Does the Glalie/Steelix in the ORAS demo have a 100% capture rate?

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I've seen lots of people get it with one pokeball. So if I don't weaken it and throw a pokeball will it catch 100%.

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YES,
They are meant to catch.No matter what you do ,It will catch.If you faint the Pokemon,It will respond.
Hoped I helped.

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Well that makes it very easy, I bet it's gonna be shiny:D