PokéBase - Pokémon Q&A
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Just what moves can It learn because I want a good Mightyena as one has saved me A LOT, and I want to repay it with a spot on my team :D!

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2 Answers

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Well, as you know, in the beginning of the game you see one that knows a fang move (Ice Fang, for instance) On my two accounts, one knew Fire Fang and the other knew Ice Fang, so I'm guessing they can know Thunder Fang as well. But, past that, I have no clue what other moves they may know. Hope this helps and sorry that I don't know more.

~Metagross2097 AKA Themysticaltaco

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Whenever you find a Pokemon hiding in the grass, there is a chance they will have an egg move. So whenever you see a poochyena hiding in the grass, it might have an egg move.

Here is a list of Poochyena's egg moves (go down to were it says egg moves)

Or look at this list
Astonish
Covet
Fire fang
Ice fang
Leer
Me first
Play rough
Poison fang
Sleep talk
Snatch
Sucker punch
Thunder fang
Yawn

Also, for the first Poochyena that you test the Dexnav on with May, I think it will only have the moves
Thunder fang
Ice fang
Fire fang

Source

Hope I helped

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Also, I'm not sure but Poochyena might have the fang move depending on your starter for the tutorial.