Meta Battle Subway PokeBase - Pokemon Q&A
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In New Mauville, which you can access after you defeat or capture kyogre/groudon. You just have to speak with Wattson in the centre of Mauville City and he will allow you to enter anytime you want.

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In New Mauville, Same for Probopass as well.

http://bulbapedia.bulbagarden.net/wiki/New_Mauville

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