PokéBase - Pokémon Q&A
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I need 5 for 3 Growlithe and 2 Vulpix

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I just use super training

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The Red Shard cannot be found using Rock Smash.
Source

Here are all the places where you can find it.

Hope I helped :)

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So I'll just have to leave it up to super training
Or get it in the other locations for some