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>Weather Ball is unaffected by Normalize, Pixilate, Refrigerate, and Aerilate. ~ Bulbapedia

Weather Ball will be a Water-type move. This is because Weather Ball instantly changes type once weather goes up. So, when Mega Glalie uses it in the Rain, it is in fact using a Water-type move.

If there is no weather active, then Weather Ball is affected by Refrigerate because it stays a Normal-type move.

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