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I have Black2. I was playing when I caught an Eelektrik. Here's the EV. chain:
Tynamo (Lv. 39) Eelektrik (Use Thunderstone) Eelektross
But I am pretty sure I got an Eelektross by leveling up! I don't get it.

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It is impossible for Eelektrik to evolve into Eelektross by level up, it must be with a Thunder Stone. The only way for it to evolve by levelling up would be to hack/glitch/modify your game.

Source: Experience, and both the DB and Serebii's evolution pages for Eelektross.

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