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Is it a sign that my Pokémon's EVs are full, when carbos and else that kind of medicine have no effect?

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Is it? I don't know are my Pokémon EVs full, so I'm afraid of using rare candies.

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No it does not mean you have max EVs. The way Carbos and others like it work is that they increase the respective stat by 10 points until the Pokemon hits the 100th point EVs in that stat. So using the Carbos will raise your Speed EVs until you hit 100 EVs in that stat, for example.

Source: Knowledge and Serebii

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