PokéBase - Pokémon Q&A
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Decidueye: Spirit Shackle
Incineroar: Darkest Lariat and Throat Chop (Throat Chop is only obtainable at Level 1. WHY???)
Primarina: Sparkling Aria

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Throat Chop is available to the Sneasel line...
I just found it in breeding

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Like Karma said, throat chop isn't a signature move. Each starter still has only one signature move.

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