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I'm currently planning more teams now.

Its only location is Abundant Shrine, but I can't answer this question because I don't know when the player gains access to it.

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You can find Vulpix in the Abundant Shrine, which is right before the Elite 4, after victory road.

Source: http://www.azurilland.com/black2_white2/walkthrough/pokemon-league/4200-optional-abundant-shrine

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Can you be more confirm? Like giving sources and a detailed anwser? Also, I'm not sure what do you mean by thinking.
Sorry, but i edited now.
Hope it's more helpful.