PokéBase - Pokémon Q&A
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I don't mean Pokemon that are good for competitive I mean Pokemon that would be part of a police department or a superhero side kick

closed with the note: Way too open and vague
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Not entirely sure if this question is allowed, but Growlithe and Arcanine serve on police forces and police officer teams in-game.
Machoke and Vigoroth are shown at the beginning RUBY, SAPHIRE, and EMERALD helping to move the protagonist in.
Machoke are shown in ORAS delivering things and helping you move in
Stoutland helps find lost children and takes care of them, if that's what you mean. anyway, it's closed so it wouldn't make a difference