PokéBase - Pokémon Q&A
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I'm pretty sure it won't get EV's, but will it not learn a move set to be learned at that level?

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Pokémon don’t gain EVs from leveling up in the first place.
Edit: (Oh oops)
Yes they do

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The Pokemon won't gain EVs, as you didn't earn them, but it will learn a move if it was supposed to learn that move at that level.

Source: Experience in numerous generations

Hope I helped!

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Also, is there a point to leveling up a Pokemon that has Max EVs and has learned all their moves, what's the point, do they earn anything?