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My piggy wants to enter the tournament, sooo help her guys...

Munna learnset

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Munna (M) @ Eviolite
Trait: Synchronize
EVs: 68 HP / 240 Def / 160 SDef / 8 Spd
Modest Nature (+SAtk, -Atk)
- Stored Power
- Barrier
- Calm Mind
- Hidden Power [Fighting]

Solid enough defenses with Eviolite, especially after Barrier and Calm Mind. These moves will not only increase Munna's defensive power, but also its offensive power thanks to Stored Power. HP Fighting is there to hit Dark types. You get good defenses with the EVs, and even a bit to go in the Speed category. Synchronize is the most useful ability.

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Munna (F) @ SilverPowder/Hard Rock/Miracle Seed
EV's: 300 HP / 250 SpAtk / 100 Atk
Trait: Forewarn
Protect/Rock Slide
Signal Beam/Dream Eater
Nightmare/Energy Ball

Hypnosis allow's you to set up Nightmare, good for stalling with Protect and Signal Beam covers your Dark Type Disadvantage. If you want to be a bit stronger or hardcore Then use Rock Slide, Energy Ball, Dream Eater or Signal Beam, Dream Eater would be better and of course Hypnosis.