PokéBase - Pokémon Q&A
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Yes, he can lurn TM endure. The problem is eventually it will fail.

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Yeah, but my strategy is perfect. Protect, Endure, Toxic, Dig.
That won't work - if you use Protect then Endure the failure rate still rises. See http://pokemondb.net/pokebase/1046/does-using-protect-and-then-detect-work
And I thought I had the perfect strategy. Thanks Pokemaster, I'll get in another move.
I was so dissapointed when I tried that strategy. I found a whole team who could do it, trained them and then failed.