PokéBase - Pokémon Q&A
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You can find it on Route 211 (the part near Eterna City), but you need Rock Climb and Rock Smash.

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There are two ways to get the Psychic TM in Platinum:

  1. You can buy multiple copies at the Veilstone City Game Corner Prize Building. Each copy costs 10,00 coins.

  2. You can find one free Psychic TM on the ground on Route 211. It's on a ledge locked behind breakable rocks and a Rock Climb spot. So you'll need to be able to use Rock Smash & Rock Climb outside of battle.

This tutorial has step-by-step screenshots on how to reach the TM on Route 211.

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You can get at the game arcade for what like 10000 coins.By the way Mew :3 where is it on route 211 I've never seen it.

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