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Let's say that if my Ferrothorn uses Toxic on a Starmie. Then it uses Reflect Type on my Ferrothorn. Will my Starmie be Poisoned? Since Poison doesn't affect Steel types.

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It will still be poisoned, as technically it changes into a steel type after getting poisoned.
EDIT: tested it on PO, starmie's still gets poisoned

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And I would assume the same goes for Fire type and Burn.