Smeargle with Sketch
Chatot with Chatter
Sketch and Chatter the only moves that are truly exclusive to one Pokémon legitimately.
Here is the Link.
Black Kyurem and White Kyurem with Freeze Shock and Ice Burn count here too, because those Moves are yet to be released, but are for those forms.
Pokemon and their Signature Moves
" Volt Tackle - Pichu/Pikachu/Raichu
Pay Day - Meowth/Persian
Kinesis - Kadabra/Alakazam
Barrage - Exeggcute/Exeggutor
Bone Club - Cubone/Marowak
Bonemerang - Cubone/Marowak
Mega Kick - Hitmonlee
Softboiled - Chansey/Blissey*
Lovely Kiss - Jynx
Conversion - Porygon/Porygon2/Porygon-Z
Conversion 2 - Porygon/Porygon2/Porygon-Z
Psystrike - Mewtwo
Octazooka - Octillery
Present - Delibird
Sketch - Smeargle
Triple Kick - Hitmontop
Milk Drink - Miltank
Aeroblast - Lugia
Sacred Fire - Ho-Oh
Smellingsalt - Makuhita/Hariyama
Ice Ball - Spheal/Sealeo/Walrein
Mist Ball - Latias
Luster Purge - Latios
Doom Desire - Jirachi
Psycho Boost - Deoxys
Attack Order - Vespiquen
Defend Order - Vespiquen
Heal Order - Vespiquen
Chatter - Chatot
Roar of Time - Dialga
Spacial Rend - Palkia
Magma Storm - Heatran
Crush Grip - Regigigas
Shadow Force - Giratina*
Lunar Dance - Cresselia
Manaphy - Heart Swap
Darkrai - Dark Void
Seed Flare - Shaymin
Judgement - Arceus
Searing Shot - Victini
V-Create - Victini
Heat Crash - Tepig/Pignite/Emboar
Storm Throw - Throh
Night Daze - Zorua/Zoroark
Tail Slap - Minccino/Cinccino
Horn Leech - Sawsbuck
Electroweb - Joltik/Galvantula
Gear Grind - Klink/Klang/Klinklang
Shift Gear - Klink/Klang/Klinklang
Head Charge - Bouffalant
Fiery Dance - Volcarona
Sacred Sword - Cobalion/Terrakion/Virizion/Keldeo
Fusion Flare - Reshiram
Blue Flare - Reshiram
Fusion Bolt - Zekrom
Bolt Strike - Zekrom
Glaciate - Kyurem
Secret Sword - Keldeo
Relic Song - Meloetta
Techno Blast - Genesect"
Credit to Pokemaster for this information. Good job Pokemaster!
