PokéBase - Pokémon Q&A
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Pick-up has nothing to do with hidden items. Heres hows pick-up works

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Beat me to it. I'll upvote you.
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The ability pick up doesn't pick up items around you, it really just gives you a free item after every battle. The item differs on the pokemon's level, so the higher the level, the rarer the item picked up.

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