PokéBase - Pokémon Q&A
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By the Odd Keystone. A man on the left of Hearthome City route gives it to you and on the right route of Hearthome you have to put it in a collapsed tower. Then go underground and meet 32 friends and come back and Spiritomb will be their. Good luck catching him!

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all in one shot (meeting the 32 people underground)
No, you can do it throughout a period of time.
do I have to trade a trap etc. it never says I met anyone in the underground.