PokéBase - Pokémon Q&A
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In Giant Chasm, when you've caught Kyurem.
>Kyurem drops it when the player catches it in Giant Chasm. -Bulbepedia


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i was about to answer this then i accidently clicked away and when i came back you had answered it
...sorry if i was to quick :P
thanks:)
no problem happy to help :D