Meta Battle Subway PokeBase - Pokemon Q&A
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He is in Mr. Mortar (north Johto). Go in and surf, go up the waterfall, and find your way through the cave.

Make sure you have an empty spot in your party because when you defeat him, he will give you Tyrogue.

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haha mr. mortar
it's mt. mortar
plus here's a handy dandy video from youtube