PokéBase - Pokémon Q&A
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No. Sucker Punch will fail both times. The first turn, they technically aren't attacking. The second turn, you will fail as the opponent will be slower than you, priority wise.

Source: Someone on Showdown that has tried it.

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No, actually, the first move succeed. I just tried after read you answer, but it works. Actually, thank god I tried, because it was a salamence 2x ATK 1.5x Spe in front of me, with just 20% of HP.
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The first move, before it highs, it works!!!

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