This is a complete list as of Gen 5:
x4 weak to ground
Rotom-H(but it has levitate), Magcargo, Hetran, Magnemite/Magneton/Magnezone, aron/larion/aggron, shieldon/bastiodon, and probopass
x4 weak to water
Numul/Camerupt, Magcargo, Geodude/Graveler/Golem, Onix, Rhyhorn/Rhydon/Rhyperior, Larvitar/Pupitar, aron/larion/aggron, shieldon/bastiodon, and probopass
x4 weak to rock
Moltres, Charizard, Ho-Oh, Larvesta/Volcorona, Arcticuno, Delibird, Butterfree, Scyther, Ledyba/Ledian, Yanma/Yanmega, Beautifly, Masquerain, Ninjask, Mothim, and Combee/Vespiquen
x4 weak to grass
Omanye/Omastar, Kabuto/Kabutops, Relicanth, Corsola, Tirtouga/Carracosta, Wooper/Quagsire, Marshtomp/Swampert, Barboach/Whishcash, Gastrodon, Palpitoad/Seismitoad, Geodude/Graveler/Golem, Onix, Rhyhorn/Rhydon/Rhyperior, and Larvitar/Pupitar
x4 weak to electric
Gyarados, Mantyke/Mantine, Wingull/Pelliper, and Ducklett/Swanna
x4 weak to fire
Snover/Abamosnow, Paras/Parasect, Wormadam (Plant Cloak), Sewaddle/Swadloon/Leavanny, Forretress, Scizor, Wormadam (trash cloak), Escavalier, Durant, Genesect, and Ferroseed/Ferrothorn
x4 weak to flying
Breloom, Virizion, Paras/Parasect, Wormadam (Plant Cloak), Sewaddle/Swadloon/Leavanny, and Heracross
x4 weak to ice
Torterra, Hoppip/Skiploom/Jumpluff, Tropius, Shaymin (sky form), Gligar/Gliscor, Landorus, Vibrava/Flygon, Gibble/Gabite/Garchomp, Dragonite, Altaria, Salamance, and Rayquaza
x4 weak to bug
Exeggcute/Exeggcutor, Celebi, Nuzleaf/Shiftry, and Cacturne
x4 weak to fighting
Sneseal/Weavile, Tyranitar, and Pawniard/Bisharp
x4 weak to psychic
Croagunk and Toxicroak
That's 115 pokemon with x4 weaknesses (if I counted right).
Magcargo, Paras/Parasect, Wormadam (Plant Cloak), Sewaddle/Swadloon/Leavanny, Geodude/Graveler/Golem, Onix, Rhyhorn/Rhydon/Rhyperior, Larvitar/Pupitar, aron/larion/aggron, shieldon/bastiodon, and probopass each have two x4 weaknesses!