PokéBase - Pokémon Q&A
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You catch it in the Distortion World. It's part of the main storyline, so you can't miss it. After you defeat Candice, go through Team Galactic's plans, and journey up to Spear Pillar via Mt. Coronet, battle through the Galactic bosses, enter and conquer your way through the Distortion World, you should met Giratina at the end.

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