PokéBase - Pokémon Q&A
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You definitely need to explain what you mean.
Pokeball, by that I mean the specific, not general pokeballs.
Do you mean VOLTROB?

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I'm assuming you mean the Special Pokeballs:

  • Premier Balls: Buy 10 PokeBalls, any Pokemart
  • Repeat Ball: Canalave City, Pokemon League, Pokemon News Press
  • Timer Ball: Snowpoint City, Canalave City, Celestic Town, Pokemon League, Pokemon News Press
  • Nest Ball: Eterna City, Hearthome City, Pastoria City, Pokemon League, Pokemon News Press
  • Net Ball: Eterna City, Hearthome City, Solaceon City, Pokemon League, Pokemon News Press
  • Dive Ball: Pokemon News Press
  • Luxury Ball: Sunyshor City, Pokemon League, Pokemon News Press
  • Heal Ball: Floroma Town, Eterna City, Oreburgh City, Hearthome City, Jubilife City, Pokemon League, Pokemon News Press
  • Quick Ball: Pastoria City, Canalave City, Snowpoint City, Pokemon League, Pokemon News Press
  • Dusk Balls: Solaceon City, Pastoria City, Snowpoint City, Pokemon League, Pokemon News Press

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Nope, she is probably asking about Voltorbs.