Female Lucario and male Blaziken for blaze kick on riolu, and female pidgeot and male staraptor for brave bird on pidgy?
Female Lucario and male Blaziken would work, but you can get blaze kick for lucario as an egg move.
For female pidgeot and male staraptor, it would work too, but you can get brave bird too for pigeot as an egg move.
I think these combinations would work if you could get the needed pokemon.
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